Sodium Permanganate Msds 1t5q67

Chongqing Changyuan Chemical Corporation Limited (formerly Chongqing Jialing Chemical Products Limited) Dujiaba Industrial Park, Rongchang County, Chongqing China 402460 www.changyuancorp.com Tel: +86-23-67957983 Fax: +86-23-67959523

MATERIAL SAFETY DATA SHEET SODIUM PERMANGANATE SOLUTION 40% Section 1 Chemical Product and Company identification Product Name: Description: Company Name: Company Address: Emergency Number: Fax Number: Email Address: Web Address:

Sodium permanganate solution 40% 40% minimum solution of NaMnO4 Chongqing Changyuan Chemical Corporation Limited Dujiaba Industrial Park, Rongchang County, Chongqing, China +86 23 46797156 +86 23 67959523 [email protected] http://en.changyuancorp.com

Section 2 Composition Chemical name Sodium permanganate

Assay (%) 40.0-40.4

CAS No. 10101-50-5

Identification: Sodium permanganate

Section 3 Hazards Identification Classification:

CLASS 5.1: Oxidizing material.

Primary Route of Entry: Potential Acute Health Hazard:

Inhalation, Ingestion, Skin Very hazardous in case of skin (irritant), or eye (irritant). Hazardous in case of skin , of ingestion, of inhalation. Prolonged exposure may result in skin burns and ulcerations. Over-exposure by inhalation may cause respiratory irritation. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally blistering.

Potential Chronic Health Effects:

CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition.

Environmental Hazard:

No data available

Explosive Hazard:

May explode upon with concentrated sulfuric acid, ammonium salts, peroxides, glycerol, ethanol, ether, sulfur, phosphorous, etc. In acidic condition, may react violently and cause fire upon with organic material, sulfur, carbon, reducing agent, flammables.

Section 4 First Aid Measures Sodium Permanganate MSDS

Page 1/6, Rev 12/09

Chongqing Changyuan Chemical Corporation Limited (formerly Chongqing Jialing Chemical Products Limited) Dujiaba Industrial Park, Rongchang County, Chongqing China 402460 www.changyuancorp.com Tel: +86-23-67957983 Fax: +86-23-67959523

Eye :

Check for and remove any lenses. Immediately flush eyes with running water for at least 15 minutes, keep eyelids open. Cold water may be used. Do not use an eye ointment. Seek medical attention.

Skin :

After with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used. Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash contaminated clothing before reusing.

Serious Skin :

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.

Inhalation:

Allow the victim to rest in a well ventilated area. Seek immediate medical attention.

Serious Inhalation:

Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, ister oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical attention.

Ingestion:

Do not not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, ister oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical attention.

Serious Ingestion:

Not available

Section 5 Fire Fighting Measures Flammability of the Product: Auto-Ignition Temperature: Flash Points: Products of Combustion: Fire Hazards: Special Remarks: Fire Fighting Precautions: Fire Fighting Methods/Agents:

Non flammable. Not Applicable. Not Applicable. Metallic oxides. Highly flammable in presence of combustible materials. When heated to decomposition it emits irrigating fumes. Wear protective cloth (suit, gloves, goggles, and boots) and a self contained breathing apparatus. Apply flooding quantity of water.

Section 6 Accidental spill measures Spill Treatment:

Persons not wearing protective equipment and clothing should be Sodium Permanganate MSDS

Page 2/6, Rev 12/09

Chongqing Changyuan Chemical Corporation Limited (formerly Chongqing Jialing Chemical Products Limited) Dujiaba Industrial Park, Rongchang County, Chongqing China 402460 www.changyuancorp.com Tel: +86-23-67957983 Fax: +86-23-67959523 restricted from spill areas until clean-up has been completed. Wear splash goggles, full protective suit, boots and gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product Oxidizing material. (1) Ventilate the spill area. Confine spill in a pit or behind a holding dam of sand or soil. (2) Dilute to approximately 6.0% with water then reduce with sodium thiosulfate, a bisulfite or a ferrous salt solution. Bisulfite or ferrous salt may require dilute sulfuric acid (10%), to promote reduction. (3) Adjust pH to neutral with Sodium Carbonate if required. (4) Decant or filter solution and deposit sludge in an approved landfill. (5) To clean contaminated floors, flush with an abundant quantity of water and treat collected water as described above. (6) Dispose of all waste according to all federal, state and local regulations. Unused material is a hazardous waste: D001- Ignitable. Do not wash or pour sodium permanganate aqueous solution into any surface waters or streams or directly into sewers. Eliminate all ignition sources. Call for assistance on disposal. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

Section 7 Handling and Storage Precautions:

Keep away from heat. Keep away from sources of ignition. Keep away from combustible material. Empty containers pose a fire risk; evaporate the residue under a fume hood. Ground all equipment containing material. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid with skin and eyes. Keep away from incompatibles such as reducing agents, organic materials, metals, acids, moisture.

Storage:

Keep in a cool, dry, ventilated area. Ground all equipment containing material. Containers should be closed. Avoid mixing with impurities like organic material, flammables, etc. Store in separate safety cabinet or room away from acids, organic material, flammables, reducing agent, reactive metal powders, autoflammables, etc. Storage facilities should be equipped with suitable material to absorb the spills.

Section 8 Exposure control/Personal Protection Maximum Exposure:

(China) MAC 0.2mg[MnO2]/m3. (United States) TLV-TWA:ACGIH 5mg[Mn]/m3 (Russian Federation) 5mg/m3

Monitoring Method:

Phosphoric acid – sodium permanganate colorimetry, cold vapor atomic absorption spectrometry

Engineering Controls:

Use process enclosures, local exhaust ventilation, provide eyewash in working area or other engineering controls to keep airborne levels Sodium Permanganate MSDS

Page 3/6, Rev 12/09

Chongqing Changyuan Chemical Corporation Limited (formerly Chongqing Jialing Chemical Products Limited) Dujiaba Industrial Park, Rongchang County, Chongqing China 402460 www.changyuancorp.com Tel: +86-23-67957983 Fax: +86-23-67959523 below permitted exposure level. Respiratory Protection:

Use mist respiratory mask. In case of emergency evacuation, wear air supplied respirator.

Eye Protection:

Wear splash goggles or face shield.

Personal Protection:

Wear chemical resistant, protective clothing.

Hand Protection:

Wear protective gloves (for example, neoprene gloves)

Other Protection:

No smoking, eating or drinking in working area. Shower and change cloths after use.

Section 9 Physical and Chemical Properties Physical state and appearance: pH value: Boiling point(oC): Flash point(oC): Density (g/cm3): Vapour Pressure(kPa): Vapor Density: Critical Temperature: Soluibility: Oxidizing properties: Explosive properties:

Dark purple liquid 6~8 110oC Not available 1.375 Not available Not available Not available Miscible with water, ethanol, ethane, liquid chlorine Strong oxidizer May explode upon with concentrated sulfuric acid, ammonium salts, peroxides, glycerol, ethanol, ether, sulfur, phosphorous, etc.

Section 10 Stability and Reactivity Data Stability: Instability Temperature: Conditions of Instability: Incompatible substances:

Stable under normal condition. Not available. Not available. Strong reducing agents, organic materials, reactive metal powders, inflammables, combustibles, sulfur, phosphorous. Fire, high temperature Manganese oxide, oxygen Not known to occur.

Conditions to avoid: Decomposition products: Polymerization:

Section 11 Toxicological Information Routes of Entry:

Dermal . Eye . Inhalation. Ingestion.

Toxicity to Animals:

Acute oral toxicity (LD50): 1090 mg/kg [Rat]. Intravenous (LD50): 55mg/kg [Rabbit]

Chronic Effects on Humans: Other Toxic Effects on Humans:

No data available. Very hazardous in case of skin (irritant).

Sodium Permanganate MSDS

Page 4/6, Rev 12/09

Chongqing Changyuan Chemical Corporation Limited (formerly Chongqing Jialing Chemical Products Limited) Dujiaba Industrial Park, Rongchang County, Chongqing China 402460 www.changyuancorp.com Tel: +86-23-67957983 Fax: +86-23-67959523 Hazardous in case of skin (permeator), of ingestion, of inhalation. Special Remarks on Toxicity to Animals: No data available. Special Remarks on Chronic Effects on Humans: No data available. Special Remarks on other Toxic Effects on Humans: Exposure can cause nausea, headache and vomiting. Material is corrosive to the mucous membranes.

Section 12 Ecological information Ecotoxicity:

No data available.

Products of Biodegradation:

Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Biodegradation Products:

The product itself and its products of degradation are not toxic. Special Remarks on the Products of Biodegradation: Not available.

Section 13 Disposal considerations Waste Disposal: Disposal Method:

D001 Hazardous waste Please follow procedures in section 6

Section 14 Transportation information UN number: Packing group: Hazard Class: DOT shipping Name:

3214 II Oxidizer Permanganates, inorganic, aqueous solution n.o.s. (Sodium Permanganate)

Section 15 Regulatory information Chinese Regulations “Dangerous Chemical Goods Safety Management Regulation”, State Council Order No 344 issued at 26 January 2002, stated the safety requirement of production, usage, transportation, loading and unloading of hazardous chemicals. “Common Hazardous Chemicals Classification and Labelling” (GB13690-1992), classified sodium permanganate as a class 5.1 oxidizing material “New Edition of Dangerous Chemical Safety Manual”, specified the safety requirement of production, usage, storage, transportation, destruction and fire safety of inflammable and explosive chemicals. “Common Hazard Chemicals Storage General Principle” (GB15603-1995) specified the requirement of warehousing, storage and conservation of hazardous chemicals.

US Regulations Toxic Substances Control Act:

All components of this product are listed in the Toxic Substance Control Act inventory

Sodium Permanganate MSDS

Page 5/6, Rev 12/09

Chongqing Changyuan Chemical Corporation Limited (formerly Chongqing Jialing Chemical Products Limited) Dujiaba Industrial Park, Rongchang County, Chongqing China 402460 www.changyuancorp.com Tel: +86-23-67957983 Fax: +86-23-67959523

Comprehensive Environmental Response Compensation and Liability Act: Not Listed Hazardous Materials Identification System Health: 3 Flammability: 0 Reactivity: 0 Protective Equipment: Gloves. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Splash goggles.

Section 16 Other information Other Special Considerations: Not available. The Chongqing Changyuan Chemical Corporation Limited (“Changyuan Chemical”) urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this MSDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/'s responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/'s duty to determine the conditions necessary for the safe use of this product. The information herein is supplied upon the condition that the persons receiving same will make their own determination as to its suitability for their purposes prior to use. In no event will Changyuan Chemical be responsible for damages of any nature whatsoever resulting from the use of or reliance upon the information herein or the product to which that information refers. Nothing contained herein is to be construed as a recommendation to use any product, process, equipment or formulation in conflict with any patent, and Changyuan Chemical makes no representation or warranty, express or implied, that the use thereof will not infringe any patent. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT.

Sodium Permanganate MSDS

Page 6/6, Rev 12/09