Chemlok 205 30396b

MATERIAL SAFETY DATA SHEET 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product name: Product Use/Class:

CHEMLOK 205 ADHESIVE AND/OR PRIMER

LORD Corporation 111 LORD Drive Cary, NC 27511-7923 Telephone: 814 868-0924 Non-Transportation Emergency: 814 763-2345 Chemtrec 24 Hr Transportation Emergency No. 800 424-9300 (Outside Continental U.S. 703 527-3887)

EFFECTIVE DATE: 01/03/2013

2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name

CAS Number

Weight % Less Than

ACGIH TLVTWA

ACGIH TLVSTEL

OSHA PELTWA

OSHA PELCEILING

Skin

Methyl isobutyl ketone

108-10-1

60.0 %

50 ppm

75 ppm

410 mg/m3 100 ppm

N.E.

N.A.

Xylene

1330-20-7

15.0 %

100 ppm

150 ppm

435 mg/m3 100 ppm

N.E.

N.A.

Titanium dioxide

13463-67-7

10.0 %

10 mg/m3

N.E.

15 mg/m3

N.E.

N.A.

Ethyl benzene

100-41-4

5.0 %

20 ppm

N.E.

435 mg/m3 100 ppm

N.E.

N.A.

Methyl ethyl ketone

78-93-3

5.0 %

200 ppm

300 ppm

590 mg/m3 200 ppm

N.E.

N.A.

Propylene glycol monomethylether

107-98-2

5.0 %

100 ppm

150 ppm

N.E.

N.E.

N.A.

Carbon black

1333-86-4

1.0 %

3 mg/m3

N.E.

3.5 mg/m3

N.E.

N.A.

Ethyl alcohol

64-17-5

1.0 %

N.E.

1,000 ppm

1,900 mg/m3 1,000 ppm

N.E.

N.A.

N.A. - Not Applicable, N.E. - Not Established, S - Skin Designation

3. HAZARDS IDENTIFICATION *** EMERGENCY OVERVIEW ***: Gray Liquid, with Solvent odor. Flammable liquid and vapor. Vapor harmful; may affect the brain or nervous system causing dizziness, headache or nausea. May cause skin and eye irritation. May cause respiratory tract irritation. EFFECTS OF OVEREXPOSURE - EYE : EFFECTS OF OVEREXPOSURE - SKIN :

May cause eye irritation. May cause skin irritation.

EFFECTS OF OVEREXPOSURE - INHALATION: Possible irritation of the respiratory system can occur causing a variety of symptoms such as dryness of the throat, tightness of the chest, and shortness of breath. May cause central nervous system depression characterized by the following progressive steps: headache, dizziness, staggering gait, confusion, unconsciousness or coma. May cause respiratory tract irritation. EFFECTS OF OVEREXPOSURE - INGESTION: entry in industrial or commercial uses.

Harmful if swallowed. Ingestion is not an expected route of

300000001175

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Product: CHEMLOK 205,

Effective Date: 01/03/2013

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: May cause liver or kidney damage. May affect the gastrointestinal system. May affect the blood and blood-forming organs. Repeated or prolonged solvent overexposure may result in permanent central nervous system damage. Prolonged or repeated may result in dermatitis. Ethylbenzene has been classified by IARC as a possible human carcinogen (Group 2B) and reported by NTP to show clear evidence for carcinogenicity in animals. IARC has designated carbon black as Group 2B - inadequate evidence for carcinogenicity in humans, but sufficient evidence in experimental animals. IARC has designated titanium dioxide (TiO2) as Group 2B – possibly carcinogenic to humans in dust form. However, a number of long term animal studies and human epidemiology studies evaluating TiO2 and workplace exposure show insufficient evidence for carcinogenic affects. EPA, NTP and OSHA do not designate TiO2 as a carcinogen and ACGIH designates TiO2 as A4 - not classifiable as a human carcinogen. TiO2 is not present in this product as a dust and no airborne exposure is expected during application. IARC has designated Methyl isobutyl ketone to be in Group 2B - possibly carcinogenic to humans. ACGIH considers Ethyl alcohol to be an A3 carcinogen (confirmed animal carcinogen with unknown relevance in humans). PRIMARY ROUTE(S) OF ENTRY: Skin , Inhalation, Ingestion, Eye

4. FIRST AID MEASURES FIRST AID - EYE : Flush eyes immediately with large amount of water for at least 15 minutes holding eyelids open while flushing. Get prompt medical attention. FIRST AID - SKIN : Flush contaminated skin with large amounts of water while removing contaminated clothing. Wash affected skin areas with soap and water. Get medical attention if symptoms occur. FIRST AID - INHALATION: Move person to fresh air. Restore and continued breathing. If breathing is difficult, give oxygen. Get immediate medical attention. FIRST AID - INGESTION: If swallowed, do not induce vomiting. Call a physician or poison control center immediately for further instructions. Never give anything by mouth if victim is rapidly losing consciousness, unconscious or convulsing.

5. FIRE-FIGHTING MEASURES FLASH POINT: 66 °F, 18 °C Setaflash Closed Cup

LOWER EXPLOSIVE LIMIT (%): 1 %(V) UPPER EXPLOSIVE LIMIT (%): 19 %(V)

AUTOIGNITION TEMPERATURE: N.D. EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam, Water Fog UNUSUAL FIRE AND EXPLOSION HAZARDS: Flammable liquid and vapor. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks, open flame, and other sources of ignition. Closed containers may rupture when exposed to extreme heat. Use water spray to keep fire exposed containers cool. During a fire, irritating and/or toxic gases and particulate may be generated by thermal decomposition or combustion. SPECIAL FIREFIGHTING PROCEDURES: Wear full firefighting protective clothing, including self-contained breathing apparatus (SCBA). Water spray may be ineffective. If water is used, fog nozzles are preferable.

6. ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Keep non-essential personnel a safe distance away from the spill area. Remove all sources of ignition (flame, hot surfaces, and electrical, static or frictional sparks). Avoid breathing vapors. Use self-contained breathing equipment. Notify appropriate authorities if necessary. Contain and remove with inert absorbent material and non-sparking tools. Avoid . Before attempting cleanup, refer to hazard caution information in other sections of the MSDS form.

7. HANDLING AND STORAGE

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Product: CHEMLOK 205,

Effective Date: 01/03/2013

HANDLING: Keep closure tight and container upright to prevent leakage. Ground and bond containers when transferring material. Avoid skin and eye . Wash thoroughly after handling. Avoid breathing of vapor or spray mists. Do not handle until all safety precautions have been read and understood. Empty containers should not be re-used. Use with adequate ventilation. Because empty containers may retain product residue and flammable vapors, keep away from heat, sparks and flame; do not cut, puncture or weld on or near the empty container. Do not smoke where this product is used or stored. STORAGE: Do not store or use near heat, sparks, or open flame. Refer to OSHA 29CFR Part 1910.106 "Flammable and Combustible Liquids" for specific storage requirements. Store only in well-ventilated areas. Do not puncture, drag, or slide container. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Sufficient ventilation in pattern and volume should be provided in order to maintain air contaminant levels below recommended exposure limits. Caution: Solvent vapors are heavier than air and collect in lower levels of the work area. Sufficient ventilation (using explosion-proof equipment) should be provided to prevent flammable vapor/air mixtures from accumulating. RESPIRATORY PROTECTION: Use a NIOSH approved chemical/mechanical filter respirator designed to remove a combination of particulates and organic vapor if occupational limits are exceeded. For emergency situations, confined space use, or other conditions where exposure limits may be greatly exceeded, use an approved air-supplied respirator. Observe OSHA regulations (29CFR 1910.134) for respirator use. SKIN PROTECTION: EYE PROTECTION: splashing may occur.

Use neoprene, nitrile, or rubber gloves to prevent skin . Use safety eyewear including safety glasses with side shields and chemical goggles where

OTHER PROTECTIVE EQUIPMENT: Use disposable or impervious clothing if work clothing contamination is likely. Remove and wash contaminated clothing before reuse. HYGIENIC PRACTICES: Wash hands before eating, smoking, or using toilet facility. Do not smoke in any chemical handling or storage area. Food or beverages should not be consumed anywhere this product is handled or stored. Wash thoroughly after handling.

9. PHYSICAL AND CHEMICAL PROPERTIES ODOR: APPEARANCE: PHYSICAL STATE: ODOR THRESHOLD:

Solvent Gray Liquid N.D.

BOILING RANGE: VAPOR PRESSURE: VAPOR DENSITY: EVAPORATION RATE:

SOLUBILITY IN H2O: pH: FREEZE POINT: COEFFICIENT OF WATER/OIL DISTRIBUTION:

Insoluble N.A. N.D. N.D.

DENSITY, LB/GL: VOLATILE BY WEIGHT: VOLATILE BY VOLUME:

80 - 141 °C N.D. Heavier than Air Faster than n-butylacetate. 7.85 lb/gal 75.42 % 87.16 %

(See section 16 for abbreviation legend)

10. STABILITY AND REACTIVITY CONDITIONS TO AVOID:

High temperatures. Sources of ignition.

INCOMPATIBILITY: Strong oxidizers, acids, bases, water. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon dioxide, carbon monoxide, chlorine, hydrogen chloride, Phosgene HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur under normal conditions.

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Product: CHEMLOK 205,

Effective Date: 01/03/2013

STABILITY: Product is stable under normal storage conditions.

11. TOXICOLOGICAL INFORMATION PRODUCT LD50

No Data No Data No Data

(ORAL) (DERMAL)

PRODUCT LC50

12. ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: No Information

13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Disposal should be done in accordance with Federal (40CFR Part 261), state and local environmental control regulations. If waste is determined to be hazardous, use licensed hazardous waste transporter and disposal facility.

14. TRANSPORT INFORMATION DOT PROPER SHIPPING NAME: DOT HAZARD CLASS: SECONDARY HAZARD: DOT UN/NA NUMBER: PACKING GROUP: EMERGENCY RESPONSE GUIDE NUMBER:

Adhesives 3 None 1133 II 128

The listed transportation classification applies to US DOT non-bulk road shipments. It does not address regulatory variations due to changes in package size, mode of shipment or other regulatory descriptors. For the most accurate shipping information, refer to your transportation/compliance department.

15. REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: AS FOLLOWS This product is considered hazardous as defined by 29 CFR 1910.1200 (OSHA HazCom Standard.) SARA SECTION 313 This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372.: Chemical Name Methyl isobutyl ketone Xylene Ethyl benzene

CAS Number 108-10-1 1330-20-7 100-41-4

Weight % Less Than 60.0 % 15.0 % 5.0 %

TOXIC SUBSTANCES CONTROL ACT: INVENTORY STATUS The chemical substances in this product are on the TSCA Section 8 Inventory. EXPORT NOTIFICATION This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States:

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Product: CHEMLOK 205,

Effective Date: 01/03/2013

NONE

16. OTHER INFORMATION HMIS RATINGS - HEALTH: 2*

FLAMMABILITY: 3

PHYSICAL HAZARD: 0

* - Indicates a chronic hazard; see Section 3 VOLATILE ORGANIC COMPOUNDS Calculated: 5.87 lb/gal5.87 lb/gal, 703 g/l EPA Method 24: 6.06 lb/gal, 726 g/l LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

DISCLAIMER The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by use of this material. It is the responsibility of the to comply with all applicable federal, state and local laws and regulations.

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