Bio Gas Seminar Report 3d4bm

CHAPTER I Introduction:The term 'biogas' is commonly used to refer to a gas which has been produced by the biological breakdown of organic matter in the absence of oxygen. The gases methane, hydrogen and carbon monoxide can be combusted or oxidized with oxygen and the resultant energy release allows biogas to be used as a fuel. In the same way that ethanol and biodiesel have been around for a long time, biogas has a long history. Back in the 13th century, explorer Marco Polo noted that the Chinese used covered sewage tanks to generate power. The author of Robinson Crusoe - Daniel Defoe – referred to biogas technologies back in the 17th century. Biogas has been used widely in the UK for centuries and back in 1895, the city of Exeter used gas from sewage to power its city street lamps. An anaerobic digester that treats farm wastes or energy crops is commonly called a 'biogas plant'.

Figure 1: Biogas plant

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CHAPTER II Biomass:a. What is biomass? Biomass is biological material derived from living, or recently living organisms. It most often refers to plants or plant-based materials which are specifically called lignocellulosic biomass. As an energy source, biomass can either be used directly via combustion to produce heat, or indirectly after converting it to various forms of biofuel. Conversion of biomass to biofuel can be achieved by different methods which are broadly classified into: thermal, chemical, and biochemical methods. Wood remains the largest biomass energy source to date; examples include forest residues (such as dead trees, branches and tree stumps), yard clippings, wood chips and even municipal solid waste. In the second sense, biomass includes plant or animal matter that can be converted into fibers or other industrial chemicals, including biofuels. Industrial biomass can be grown from numerous types of plants, including miscanthus, switchgrass, hemp, corn, poplar, willow, sorghum, sugarcane, bamboo, and a variety of tree species, ranging from eucalyptus to oil palm (palm oil). Plant energy is produced by crops specifically grown for use as fuel that offer high biomass output per hectare with low input energy. Some examples of these plants are wheat, which typically yield 7.5–8 tonnes of grain per hectare, and straw, which typically yield 3.5–5 tonnes per hectare in the UK. The grain can be used for liquid transportation fuels while the straw can be burned to produce heat or electricity. Plant biomass can also be degraded from cellulose to glucose through a series of chemical treatments, and the resulting sugar can then be used as a first generation biofuel. Biomass can be converted to other usable forms of energy like methane gas or transportation fuels like ethanol and biodiesel. Rotting garbage, and agricultural and human waste, all release methane gas—also called "landfill gas" or "biogas." Crops, such as corn and sugar cane, can be fermented to produce the transportation fuel, ethanol. Biodiesel, another transportation fuel, can be produced from left-over food products like vegetable oils and animal fats. Also, biomass to liquids (BTLs) and cellulosic ethanol are still under research.

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There is a great deal of research involving algal, or algae-derived, biomass due to the fact that it’s a non-food resource and can be produced at rates 5 to 10 times faster than other types of land-based agriculture, such as corn and soy. Once harvested, it can be fermented to produce biofuels such as ethanol, butanol, and methane, as well as biodiesel and hydrogen. The biomass used for electricity generation varies by region. Forest by-products, such as wood residues, are common in the United States. Agricultural waste is common in Mauritius (sugar cane residue) and Southeast Asia (rice husks). Animal husbandry residues, such as poultry litter, are common in the UK.

b. Biomass sources:Historically, humans have harnessed biomass-derived energy since the time when people began burning wood to make fire.[2] Even in today's modern era, biomass is the only source of fuel for domestic use in many developing countries. Biomass is all biologically-produced matter based in carbon, hydrogen and oxygen. The estimated biomass production in the world is 104.9 petagram (104.9 * 1015 g) of carbon per year, about half in the ocean and half on land. Wood remains the largest biomass energy source today; examples include forest residues (such as dead trees, branches and tree stumps), yard clippings, wood chips and even municipal solid waste. Wood energy is derived by using lignocellulosic biomass (second generation biofuels) as fuel. This is either using harvested wood directly as a fuel, or collecting from wood waste streams. The largest source of energy from wood is pulping liquor or "black liquor," a waste product from processes of the pulp, paper and paperboard industry. In the second sense, biomass includes plant or animal matter that can be converted into fibers or other industrial chemicals, including biofuels. Industrial biomass can be grown from numerous types of plants, including miscanthus, switchgrass, hemp, corn, poplar, willow, sorghum, sugarcane, bamboo, and a variety of tree species, ranging from eucalyptus to oil palm (palm oil). Based on the source of biomass, biofuels are classified broadly into two major categories. First generation biofuels are derived from sources such as sugarcane and corn starch etc. Sugars present in this biomass are fermented to produce bioethanol, an 3

alcohol fuel which furthermore can be used directly in a fuel cell to produce electricity or serve as an additive to gasoline. However, utilizing food based resource for fuel production only aggravates the food shortage problem further. Second generation biofuels on the other hand utilize non-food based biomass sources such as agriculture and municipal waste. It mostly consists of lignocellulosic biomass which is not edible and is a low value waste for many industries. Despite being the favored alternative, economical production of second generation biofuel is not yet achieved due to technological issues. These issues arise mainly due to chemical inertness and structural rigidity of lignocellulosic biomass. Plant energy is produced by crops specifically grown for use as fuel that offer high biomass output per hectare with low input energy. Some examples of these plants are wheat, which typically yield 7.5–8 tons (tonnes?) of grain per hectare, and straw, which typically yield 3.5–5 tons (tonnes?) per hectare in the UK. The grain can be used for liquid transportation fuels while the straw can be burned to produce heat or electricity. Plant biomass can also be degraded from cellulose to glucose through a series of chemical treatments, and the resulting sugar can then be used as a first generation biofuel. The main contributors of waste energy are municipal solid waste (MSW), manufacturing waste, and landfill gas. Energy derived from biomass is projected to be the largest non-hydroelectric renewable resource of electricity in the U.S between 2000 and 2020. Biomass can be converted to other usable forms of energy like methane gas or transportation fuels like ethanol and biodiesel. Rotting garbage, and agricultural and human waste, all release methane gas—also called "landfill gas" or "biogas." Crops, such as corn and sugar cane, can be fermented to produce the transportation fuel, ethanol. Biodiesel, another transportation fuel, can be produced from left-over food products like vegetable oils and animal fats. Also, biomass to liquids (BTLs) and cellulosic ethanol are still under research. There is a great deal of research involving algae, or algae-derived, biomass due to the fact that it’s a non-food resource and can be produced at rates 5 to 10 times those of other types of land-based agriculture, such as corn and soy. Once harvested, it can be 4

fermented to produce biofuels such as ethanol, butanol, and methane, as well as biodiesel and hydrogen. Efforts are being made to identify which species of algae are most suitable for energy production. Genetic engineering approaches could also be utilized to improve microalgae as a source of biofuel. The biomass used for electricity generation varies by region. Forest by-products, such as wood residues, are common in the United States. Agricultural waste is common in Mauritius (sugar cane residue) and Southeast Asia (rice husks). Animal husbandry residues, such as poultry litter, are common in the UK. As of 2015, a new bioenergy sewage treatment process aimed at developing countries is being trialed; the Omni Processor is a self-sustaining process which uses the sewerage solids as fuel in a process to convert the waste water into drinking water and with surplus electrical energy being generated for export.

Fig 2: Types of Biomass

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C. Pyramid of Biomass:"Pyramid of biomass is the graphic representation of biomass present per unit area of different tropic levels, with producers at the base and top carnivores at the tip". The total amount of living or organic matter in an ecosystem at any time is called 'Biomass'. In a terrestrial ecosystem, the maximum biomass occurs in producers, and there is progressive decrease in biomass from lower to higher tropic levels. Thus, the pyramid of biomass in a terrestrial ecosystem is upright. In an aquatic habitat the pyramid of biomass is inverted or spindle shaped where the biomass of tropic level depends upon the reproductive potential and longevity of the member.

Figure 3: upright pyramid of biomass

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d. Where does biomass come from? Carbon dioxide from the atmosphere and water from the earth are combined in the photosynthetic process to produce carbohydrates (sugars) that form the building blocks of biomass. The solar energy that drives photosynthesis is stored in the chemical bonds of the structural components of biomass. If we burn biomass efficiently (extract the energy stored in the chemical bonds) oxygen from the atmosphere combines with the carbon in plants to produce carbon dioxide and water. The process is cyclic because the carbon dioxide is then available to produce new biomass.

Fig 4: Biomass Cycle

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e. Biomass conversion process to useful energy:There are a number of technological options available to make use of a wide variety of biomass types as a renewable energy source. Conversion technologies may release the energy directly, in the form of heat or electricity, or may convert it to another form, such as liquid biofuel or combustible biogas. While for some classes of biomass resource there may be a number of usage options, for others there may be only one appropriate technology. Thermal conversion:These are processes in which heat is the dominant mechanism to convert the biomass into another chemical form. The basic alternatives of combustion, torrefaction, pyrolysis, and gasification are separated principally by the extent to which the chemical reactions involved are allowed to proceed (mainly controlled by the availability of oxygen and conversion temperature).There is a number of other less common, more experimental or proprietary thermal processes that may offer benefits such as hydrothermal upgrading (HTU) and hydro processing. Some have been developed for use on high moisture content biomass, including aqueous slurries, and allow them to be converted into more convenient forms. Some of the applications of thermal conversion are combined heat and power (CHP) and co-firing. In a typical biomass power plant, efficiencies range from 20–27%. Chemical conversion:A range of chemical processes may be used to convert biomass into other forms, such as to produce a fuel that is more conveniently used, transported or stored, or to exploit some property of the process itself. Biochemical conversion:-

Fig 5: A microbial electrolysis cell can be used to directly make hydrogen gas from plant 8

As biomass is a natural material, many highly efficient biochemical processes have developed in nature to break down the molecules of which biomass is composed, and many of these biochemical conversion processes can be harnessed. Biochemical conversion makes use of the enzymes of bacteria and other microorganisms to break down biomass. In most cases micro-organisms are used to perform the conversion process: anaerobic digestion, fermentation and composting. Other chemical processes such as converting straight and waste vegetable oils into biodiesel are transesterification. Another way of breaking down biomass is by breaking down the carbohydrates and simple sugars to make alcohol. However, this process has not been perfected yet. Scientists are still researching the effects of converting biomass.

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CHAPTER III ANAEROBIC DIGESTION:Anaerobic digestion is a collection of processes by which microorganisms break down biodegradable material in the absence of oxygen. The process is used for industrial or domestic purposes to manage waste and/or to produce fuels. Much of the fermentation used industrially to produce food and drink products, as well as home fermentation, uses anaerobic digestion. Anaerobic digestion occurs naturally in some soils and in lake and oceanic basin sediments, where it is usually referred to as "anaerobic activity". This is the source of marsh gas methane as discovered by Volta in 1776. The digestion process begins with bacterial hydrolysis of the input materials. Insoluble organic polymers, such as carbohydrates, are broken down to soluble derivatives that become available for other bacteria. Acidogenic bacteria then convert the sugars and amino acids into carbon dioxide, hydrogen, ammonia, and organic acids. These bacteria convert these resulting organic acids into acetic acid, along with additional ammonia, hydrogen, and carbon dioxide. Finally, methanogens convert these products to methane and carbon dioxide. The methanogenic archaea populations play an indispensable role in anaerobic wastewater treatments. It is used as part of the process to treat biodegradable waste and sewage sludge. As part of an integrated waste management system, anaerobic digestion reduces the emission of landfill gas into the atmosphere. Anaerobic digesters can also be fed with purposegrown energy crops, such as maize. Anaerobic digestion is widely used as a source of renewable energy. The process produces a biogas, consisting of methane, carbon dioxide and traces of other ‘contaminant’ gases. This biogas can be used directly as fuel, in combined heat and power gas engines or upgraded to natural gas-quality biomethane. The nutrient-rich digestate also produced can be used as fertilizer. With the re-use of waste as a resource and new technological approaches which have lowered capital costs, anaerobic digestion has in recent years received increased 10

attention among governments in a number of countries, among these the United Kingdom (2011), and Denmark (2011).

1. Process Many microorganisms affect anaerobic digestion, including acetic acid-forming bacteria (acetogens) and methane-forming archaea (methanogens). These organisms promote a number of chemical processes in converting the biomass to biogas.

Gaseous oxygen is excluded from the reactions by physical containment. Anaerobes utilize electron acceptors from sources other than oxygen gas. These acceptors can be the organic material itself or may be supplied by inorganic oxides from within the input material. When the oxygen source in an anaerobic system is derived from the organic material itself, the 'intermediate' end products are primarily alcohols, aldehydes, and organic acids, plus carbon dioxide. In the presence of specialised methanogens, the intermediates are converted to the 'final' end products of methane, carbon dioxide, and trace levels of hydrogen sulfide. In an anaerobic system, the majority of the chemical energy contained within the starting material is released by methanogenic bacteria as methane. Populations of anaerobic microorganisms typically take a significant period of time to establish themselves to be fully effective. Therefore, common practice is to introduce anaerobic microorganisms from materials with existing populations, a process known as "seeding" the digesters, typically accomplished with the addition of sewage sludge or cattle slurry.

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2. Process stages

Figure 6: The key process stages of anaerobic digestion There are four key biological and chemical stages of anaerobic digestion: 1. Hydrolysis 2. Acidogenesis 3. Acetogenesis 4. Methanogenesis In most cases, biomass is made up of large organic polymers. For the bacteria in anaerobic digesters to access the energy potential of the material, these chains must first be broken down into their smaller constituent parts. These constituent parts, or monomers, such as sugars, are readily available to other bacteria. The process of breaking these chains and dissolving the smaller molecules into solution is called hydrolysis. Therefore, hydrolysis of these high-molecular-weight polymeric components is the necessary first step in anaerobic digestion. Through hydrolysis the complex organic molecules are broken down into simple sugars, amino acids, and fatty acids. Acetate and hydrogen produced in the first stages can be used directly by methanogens. Other molecules, such as volatile fatty acids (VFAs) with a chain length greater than that of acetate must first be catabolised into compounds that can be directly used by methanogens.

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The biological process of acidogenesis results in further breakdown of the remaining components by acidogenic (fermentative) bacteria. Here, VFAs are created, along with ammonia, carbon dioxide, and hydrogen sulfide, as well as other byproducts. The process of acidogenesis is similar to the way milk sours. The third stage of anaerobic digestion is acetogenesis. Here, simple molecules created through the acidogenesis phase are further digested by acetogens to produce largely acetic acid, as well as carbon dioxide and hydrogen. The terminal stage of anaerobic digestion is the biological process of methanogenesis. Here, methanogens use the intermediate products of the preceding stages and convert them into methane, carbon dioxide, and water. These components make up the majority of the biogas emitted from the system. Methanogenesis is sensitive to both high and low pHs and occurs between pH 6.5 and pH 8. The remaining, indigestible material the microbes cannot use and any dead bacterial remains constitute the digestate. A simplified generic chemical equation for the overall processes outlined above is as follows: C6H12O6 → 3CO2 + 3CH4 Anaerobic digesters can be designed and engineered to operate using a number of different process configurations: 

Batch or continuous

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Temperature: Mesophilic or thermophilic

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Solids content: High solids or low solids

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Complexity: Single stage or multistage

Batch or continuous Anaerobic digestion can be performed as a batch process or a continuous process. In a batch system biomass is added to the reactor at the start of the process. The reactor is then sealed for the duration of the process.

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In its simplest form batch processing needs inoculation with already processed material to start the anaerobic digestion. In a typical scenario, biogas production will be formed with a normal distribution pattern over time. Operators can use this fact to determine when they believe the process of digestion of the organic matter has completed. There can be severe odour issues if a batch reactor is opened and emptied before the process is well completed. A more advanced type of batch approach has limited the odour issues by integrating anaerobic digestion with in-vessel composting. In this approach inoculation takes place through the use of recirculated degasified percolate. After anaerobic digestion has completed, the biomass is kept in the reactor which is then used for in-vessel composting before it is opened As the batch digestion is simple and requires less equipment and lower levels of design work, it is typically a cheaper form of digestion. Using more than one batch reactor at a plant can ensure constant production of biogas. In continuous digestion processes, organic matter is constantly added (continuous complete mixed) or added in stages to the reactor (continuous plug flow; first in – first out). Here, the end products are constantly or periodically removed, resulting in constant production of biogas. A single or multiple digesters in sequence may be used. Examples of this form of anaerobic digestion include continuous stirred-tank reactors, upflow anaerobic sludge blankets, expanded granular sludge beds and internal circulation reactors. Temperature The two conventional operational temperature levels for anaerobic digesters determine the species of methanogens in the digesters: 

Mesophilic digestion takes place optimally around 30 to 38 °C, or at ambient temperatures between 20 and 45 °C, where mesophiles are the primary microorganism present.

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Thermophilic digestion takes place optimally around 49 to 57 °C, or at elevated temperatures up to 70 °C, where thermophiles are the primary microorganisms present.

A limit case has been reached in Bolivia, with anaerobic digestion in temperature working conditions of less than 10 °C. The anaerobic process is very slow, taking more than three times the normal mesophilic time process. In experimental work at University of Alaska Fairbanks, a 1,000 litre digester using psychrophiles harvested from "mud from a frozen lake in Alaska" has produced 200–300 litres of methane per day, about 20 to 30% of the output from digesters in warmer climates. Mesophilic species outnumber thermophiles, and they are also more tolerant to changes in environmental conditions than thermophiles. Mesophilic systems are, therefore, considered to be more stable than thermophilic digestion systems. In contrast, while thermophilic digestion systems are considered less stable, their energy input is higher, with more biogas being removed from the organic matter in an equal amount of time. The increased temperatures facilitate faster reaction rates, and thus faster gas yields. Operation at higher temperatures facilitates greater pathogen reduction of the digestate. In countries where legislation, such as the Animal ByProducts Regulations in the European Union, requires digestate to meet certain levels of pathogen reduction there may be a benefit to using thermophilic temperatures instead of mesophilic. Additional pre-treatment can be used to reduce the necessary retention time to produce biogas. For example, certain processes shred the substrates to increase the surface area or use a thermal pretreatment stage (such as pasteurisation) to significantly enhance the biogas output. The pasteurisation process can also be used to reduce the pathogenic concentration in the digesate leaving the anaerobic digester. Pasteurisation may be achieved by heat treatment combined with maceration of the solids. Solids content In a typical scenario, three different operational parameters are associated with the solids content of the feedstock to the digesters:

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High solids (dry—stackable substrate)

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High solids (wet—pumpable substrate)

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Low solids (wet—pumpable substrate)

High solids (dry) digesters are designed to process materials with a solids content between 25 and 40%. Unlike wet digesters that process pumpable slurries, high solids (dry – stackable substrate) digesters are designed to process solid substrates without the addition of water. The primary styles of dry digesters are continuous vertical plug flow and batch tunnel horizontal digesters. Continuous vertical plug flow digesters are upright, cylindrical tanks where feedstock is continuously fed into the top of the digester, and flows downward by gravity during digestion. In batch tunnel digesters, the feedstock is deposited in tunnel-like chambers with a gas-tight door. Neither approach has mixing inside the digester. The amount of pretreatment, such as contaminant removal, depends both upon the nature of the waste streams being processed and the desired quality of the digestate. Size reduction (grinding) is beneficial in continuous vertical systems, as it accelerates digestion, while batch systems avoid grinding and instead require structure (e.g. yard waste) to reduce compaction of the stacked pile. Continuous vertical dry digesters have a smaller footprint due to the shorter effective retention time and vertical design. Wet digesters can be designed to operate in either a high-solids content, with a total suspended solids (TSS) concentration greater than ~20%, or a low-solids concentration less than ~15%. High solids (wet) digesters process a thick slurry that requires more energy input to move and process the feedstock. The thickness of the material may also lead to associated problems with abrasion. High solids digesters will typically have a lower land requirement due to the lower volumes associated with the moisture.[citation needed] High solids digesters also require correction of conventional performance calculations (e.g. gas production, retention time, kinetics, etc.) originally based on very dilute sewage digestion concepts, since larger fractions of the feedstock mass are potentially convertible to biogas. Low solids (wet) digesters can transport material through the system using standard pumps that require significantly lower energy input. Low solids digesters require a 16

larger amount of land than high solids due to the increased volumes associated with the increased liquid-to-feedstock ratio of the digesters. There are benefits associated with operation in a liquid environment, as it enables more thorough circulation of materials and between the bacteria and their food. This enables the bacteria to more readily access the substances on which they are feeding, and increases the rate of gas production. Complexity Two-stage, low solids, UASB digestion component of a mechanical biological treatment system near Tel Aviv; the process water is seen in balance tank and sequencing batch reactor, 2005. Digestion systems can be configured with different levels of complexity:[34] In a single-stage digestion system (one-stage), all of the biological reactions occur within a single, sealed reactor or holding tank. Using a single stage reduces construction costs, but results in less control of the reactions occurring within the system. Acidogenic bacteria, through the production of acids, reduce the pH of the tank. Methanogenic bacteria, as outlined earlier, operate in a strictly defined pH range.[37] Therefore, the biological reactions of the different species in a single-stage reactor can be in direct competition with each other. Another one-stage reaction system is an anaerobic lagoon. These lagoons are pond-like, earthen basins used for the treatment and long-term storage of manures.[38] Here the anaerobic reactions are contained within the natural anaerobic sludge contained in the pool. In a two-stage digestion system (multistage), different digestion vessels are optimised to bring maximum control over the bacterial communities living within the digesters. Acidogenic bacteria produce organic acids and more quickly grow and reproduce than methanogenic bacteria. Methanogenic bacteria require stable pH and temperature to optimise their performance.[39] Under typical circumstances, hydrolysis, acetogenesis, and acidogenesis occur within the first reaction vessel. The organic material is then heated to the required operational temperature (either mesophilic or thermophilic) prior to being pumped into a methanogenic reactor. The initial hydrolysis or acidogenesis tanks prior to the 17

methanogenic reactor can provide a buffer to the rate at which feedstock is added. Some European countries require a degree of elevated heat treatment to kill harmful bacteria in the input waste. In this instance, there may be a pasteurisation or sterilisation stage prior to digestion or between the two digestion tanks. Notably, it is not possible to completely isolate the different reaction phases, and often some biogas is produced in the hydrolysis or acidogenesis tanks. Residence time The residence time in a digester varies with the amount and type of feed material, the configuration of the digestion system, and whether it be one-stage or two-stage. In the case of single-stage thermophilic digestion, residence times may be in the region of 14 days, which, compared to mesophilic digestion, is relatively fast. The plug-flow nature of some of these systems will mean the full degradation of the material may not have been realised in this timescale. In this event, digestate exiting the system will be darker in colour and will typically have more odour. In two-stage mesophilic digestion, residence time may vary between 15 and 40 days. In the case of mesophilic UASB digestion, hydraulic residence times can be 1 hour to 1 day, and solid retention times can be up to 90 days. In this manner, the UASB system is able to separate solids and hydraulic retention times with the use of a sludge blanket. Continuous digesters have mechanical or hydraulic devices, depending on the level of solids in the material, to mix the contents, enabling the bacteria and the food to be in . They also allow excess material to be continuously extracted to maintain a reasonably constant volume within the digestion tanks. Inhibition The anaerobic digestion process can be inhibited by several compounds, affecting one of more of the bacterial groups responsible for the different organic matter degradation steps. The degree of the inhibition depends, among other factors, on the concentration of the inhibitor in the digester. Potential inhibitors are ammonia, sulfide, light metal

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ions (Na, K, Mg, Ca, Al), heavy metals, some organics (chlorophenols, halogenated aliphatics, N-substituted aromatics, long chain fatty acids), etc.[43] Feedstocks

Anaerobic lagoon and generators at the Cal Poly Dairy, United States 2003 The most important initial issue when considering the application of anaerobic digestion systems is the feedstock to the process. Almost any organic material can be processed with anaerobic digestion; however, if biogas production is the aim, the level of putrescibility is the key factor in its successful application. The more putrescible (digestible) the material, the higher the gas yields possible from the system. Feedstocks can include biodegradable waste materials, such as waste paper, grass clippings, leftover food, sewage, and animal waste. Woody wastes are the exception, because they are largely unaffected by digestion, as most anaerobes are unable to degrade lignin. Xylophalgeous anaerobes (lignin consumers) or using high temperature pretreatment, such as pyrolysis, can be used to break down the lignin. Anaerobic digesters can also be fed with specially grown energy crops, such as silage, for dedicated biogas production. In and continental Europe, these facilities are referred to as "biogas" plants. A codigestion or cofermentation plant is typically an agricultural anaerobic digester that accepts two or more input materials for simultaneous digestion. The length of time required for anaerobic digestion depends on the chemical complexity of the material. Material rich in easily digestible sugars breaks down quickly where as intact lignocellulosic material rich in cellulose and hemicellulose polymers can take much longer to break down. Anaerobic microorganisms are generally unable to break down lignin, the recalcitrant aromatic component of biomass. Anaerobic digesters were originally designed for operation using sewage sludge and manures. Sewage and manure are not, however, the material with the most potential for anaerobic digestion, as the biodegradable material has already had much of the energy content taken out by the animals that produced it. Therefore, many digesters operate with codigestion of two or more types of feedstock. For example, in a farm-based 19

digester that uses dairy manure as the primary feedstock, the gas production may be significantly increased by adding a second feedstock, e.g., grass and corn (typical onfarm feedstock), or various organic byproducts, such as slaughterhouse waste, fats, oils and grease from restaurants, organic household waste, etc. (typical off-site feedstock). Digesters processing dedicated energy crops can achieve high levels of degradation and biogas production. Slurry-only systems are generally cheaper, but generate far less energy than those using crops, such as maize and grass silage; by using a modest amount of crop material (30%), an anaerobic digestion plant can increase energy output tenfold for only three times the capital cost, relative to a slurry-only system. Moisture content A second consideration related to the feedstock is moisture content. Dryer, stackable substrates, such as food and yard waste, are suitable for digestion in tunnel-like chambers. Tunnel-style systems typically have near-zero wastewater discharge, as well, so this style of system has advantages where the discharge of digester liquids are a liability. The wetter the material, the more suitable it will be to handling with standard pumps instead of energy-intensive concrete pumps and physical means of movement. Also, the wetter the material, the more volume and area it takes up relative to the levels of gas produced. The moisture content of the target feedstock will also affect what type of system is applied to its treatment. To use a high-solids anaerobic digester for dilute feedstocks, bulking agents, such as compost, should be applied to increase the solids content of the input material. Another key consideration is the carbon:nitrogen ratio of the input material. This ratio is the balance of food a microbe requires to grow; the optimal C:N ratio is 20–30:1. Excess N can lead to ammonia inhibition of digestion. Contamination The level of contamination of the feedstock material is a key consideration. If the feedstock to the digesters has significant levels of physical contaminants, such as plastic, glass, or metals, then processing to remove the contaminants will be required for the material to be used. If it is not removed, then the digesters can be blocked and will not function efficiently. It is with this understanding that mechanical biological treatment plants are designed. The higher the level of pretreatment a feedstock requires, 20

the more processing machinery will be required, and, hence, the project will have higher capital costs. After sorting or screening to remove any physical contaminants from the feedstock, the material is often shredded, minced, and mechanically or hydraulically pulped to increase the surface area available to microbes in the digesters and, hence, increase the speed of digestion. The maceration of solids can be achieved by using a chopper pump to transfer the feedstock material into the airtight digester, where anaerobic treatment takes place. Substrate composition Substrate composition is a major factor in determining the methane yield and methane production rates from the digestion of biomass. Techniques to determine the compositional characteristics of the feedstock are available, while parameters such as solids, elemental, and organic analyses are important for digester design and operation. 3. Applications Using anaerobic digestion technologies can help to reduce the emission of greenhouse gases in a number of key ways: 

Replacement of fossil fuels

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Reducing or eliminating the energy footprint of waste treatment plants

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Reducing methane emission from landfills

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Displacing industrially produced chemical fertilizers

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Reducing vehicle movements

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Reducing electrical grid transportation losses

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Reducing usage of LP Gas for cooking

Waste treatment Anaerobic digestion is particularly suited to organic material, and is commonly used for effluent and sewage treatment. Anaerobic digestion, a simple process, can greatly reduce the amount of organic matter which might otherwise be destined to be dumped at sea, dumped in landfills, or burnt in incinerators. 21

Pressure from environmentally related legislation on solid waste disposal methods in developed countries has increased the application of anaerobic digestion as a process for reducing waste volumes and generating useful byproducts. It may either be used to process the source-separated fraction of municipal waste or alternatively combined with mechanical sorting systems, to process residual mixed municipal waste. These facilities are called mechanical biological treatment plants. If the putrescible waste processed in anaerobic digesters were disposed of in a landfill, it would break down naturally and often anaerobically. In this case, the gas will eventually escape into the atmosphere. As methane is about 20 times more potent as a greenhouse gas than carbon dioxide, this has significant negative environmental effects. In countries that collect household waste, the use of local anaerobic digestion facilities can help to reduce the amount of waste that requires transportation to centralized landfill sites or incineration facilities. This reduced burden on transportation reduces carbon emissions from the collection vehicles. If localized anaerobic digestion facilities are embedded within an electrical distribution network, they can help reduce the electrical losses associated with transporting electricity over a national grid. Power generation In developing countries, simple home and farm-based anaerobic digestion systems offer the potential for low-cost energy for cooking and lighting. From 1975, China and India have both had large, government-backed schemes for adaptation of small biogas plants for use in the household for cooking and lighting. At present, projects for anaerobic digestion in the developing world can gain financial through the United Nations Clean Development Mechanism if they are able to show they provide reduced carbon emissions. Methane and power produced in anaerobic digestion facilities can be used to replace energy derived from fossil fuels, and hence reduce emissions of greenhouse gases, because the carbon in biodegradable material is part of a carbon cycle. The carbon released into the atmosphere from the combustion of biogas has been removed by plants for them to grow in the recent past, usually within the last decade, but more typically within the last growing season. If the plants are regrown, taking the carbon out of the 22

atmosphere once more, the system will be carbon neutral. In contrast, carbon in fossil fuels has been sequestered in the earth for many millions of years, the combustion of which increases the overall levels of carbon dioxide in the atmosphere. Biogas from sewage works is sometimes used to run a gas engine to produce electrical power, some or all of which can be used to run the sewage works. Some waste heat from the engine is then used to heat the digester. The waste heat is, in general, enough to heat the digester to the required temperatures. The power potential from sewage works is limited – in the UK, there are about 80 MW total of such generation, with the potential to increase to 150 MW, which is insignificant compared to the average power demand in the UK of about 35,000 MW. The scope for biogas generation from nonsewage waste biological matter – energy crops, food waste, abattoir waste, etc. - is much higher, estimated to be capable of about 3,000 MW.[citation needed] Farm biogas plants using animal waste and energy crops are expected to contribute to reducing CO2 emissions and strengthen the grid, while providing UK farmers with additional revenues. Some countries offer incentives in the form of, for example, feed-in tariffs for feeding electricity onto the power grid to subsidize green energy production. In Oakland, California at the East Bay Municipal Utility District’s main wastewater treatment plant (EBMUD), food waste is currently codigested with primary and secondary municipal wastewater solids and other high-strength wastes. Compared to municipal wastewater solids digestion alone, food waste codigestion has many benefits. Anaerobic digestion of food waste pulp from the EBMUD food waste process provides a higher normalized energy benefit, compared to municipal wastewater solids: 730 to 1,300 kWh per dry ton of food waste applied compared to 560 to 940 kWh per dry ton of municipal wastewater solids applied. Grid injection Biogas grid-injection is the injection of biogas into the natural gas grid. The raw biogas has to be previously upgraded to biomethane. This upgrading implies the removal of contaminants such as hydrogen sulphide or siloxanes, as well as the carbon dioxide. Several technologies are available for this purpose, being the most widely implemented 23

the pressure swing adsorption (PSA), water or amine scrubbing (absorption processes) and, in the last years, membrane separation. As an alternative, the electricity and the heat can be used for on-site generation, resulting in a reduction of losses in the transportation of energy. Typical energy losses in natural gas transmission systems range from 1–2%, whereas the current energy losses on a large electrical system range from 5–8%. In October 2010, Didcot Sewage Works became the first in the UK to produce biomethane gas supplied to the national grid, for use in up to 200 homes in Oxfordshire. Vehicle fuel After upgrading with the above-mentioned technologies, the biogas (transformed into biomethane) can be used as vehicle fuel in adapted vehicles. This use is very extensive in Sweden, where over 38,600 gas vehicles exist, and 60% of the vehicle gas is biomethane generated in anaerobic digestion plants. Fertiliser and soil conditioner The solid, fibrous component of the digested material can be used as a soil conditioner to increase the organic content of soils. Digester liquor can be used as a fertiliser to supply vital nutrients to soils instead of chemical fertilisers that require large amounts of energy to produce and transport. The use of manufactured fertilisers is, therefore, more carbon-intensive than the use of anaerobic digester liquor fertiliser. In countries such as Spain, where many soils are organically depleted, the markets for the digested solids can be equally as important as the biogas. Cooking gas By using a bio-digester, which produces the bacteria required for decomposing, cooking gas is generated. The organic garbage like fallen leaves, kitchen waste, food waste etc. are fed into a crusher unit, where the mixture is conflated with a small amount of water. The mixture is then fed into the bio-digester, where the bacteria decomposes it to produce cooking gas. This gas is piped to kitchen stove. A 2 cubic meter bio-digester can produce 2 cubic meter of cooking gas. This is equivalent to 1 kg of LPG. The notable advantage of using a bio-digester is the sludge which is a rich organic manure. 24

Combustion in dedicated power and CHP plants:Biomass can be burned to produce electricity and CHP via a steam turbine in dedicated power plants. The typical size of these plants is ten times smaller (from 1 to100 MW) than coal-fired plants because of the scarce availability of local feedstock and the high transportation cost. A few large-scale such plants are in operation. The small size roughly doubles the investment cost per kW and results in lower electrical efficiency compared to coal plants. Plant efficiency is around 30% depending on plant size. This technology is used to dispose of large amounts of residues and wastes (e.g bagasse). Using highquality wood chips in modern CHP plants with maximum steam temperature of 540°C, electrical efficiency can reach 33%-34% (LHV), and up to 40% if operated in electricity-only mode. Fossil energy consumed for bio-power production using forestry and agriculture Products can be as low as 2%-5% of the final energy produced. Based on life-cycle assessment, net carbon emissions per unit of electricity are below 10% of the emissions from fossil fuel-based electricity. When using MSW, corrosion problems limit the steam temperature and reduce electrical efficiency to around22%. New CHP plant designs using MSW are expected to reach 28%-30% electrical efficiency, and above 85%-90% overall efficiency in CHP mode if good matching is achieved between heat productions and demand. Usage Biomass is an important source of energy ing for about one third of the total fuel used in our country and in about 90% of the rural households. The widespread use of biomass is for household cooking and heating. The types of biomass used are agricultural waste, wood, charcoal or dried dung. 4. Advantages:

Available locally and to some extent abundantly.



It is a relatively clean fuel when compared to fossil fuels. In a way biomass also cleans our environment by trapping Carbon di-oxide.

5. Disadvantages:

Drudgery involved in collection of fuel 25



During indoor cooking and in the absence of sufficient ventilation fuels such as dung cause air pollution which is a serious health hazard.



Unsustainable and inefficient use of biomass often leads to destruction of vegetation and hence environmental degradation.

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CHAPTER IV Components of Biogas power plant The components of a biogas unit are: 1.

Reception tank

2.

Digester or fermenter

3.

Gas holder

4.

Overflow tank

1. Size of biogas unit The size of a biogas unit depends on several factors, which are: 1.

The amount and type of organic waste to be disposed in the digester

2.

The objective of treating the organic waste (the production of energy and/or organic fertilizer)

3.

Demand of natural gas and consumption pattern

4.

On-site nature of the soil and the level of ground water

5.

Air temperature in the region and wind direction throughout the different seasons

6.

The training level of the staff on farm and home regarding operation of biogas units

The amount of manure fed into a digester each day has an important effect on its operation. This is measured by volume added in relation to the volume of the digester, but the actual quantity fed to the digester also depends on the temperature at which the digester is maintained. In order to determine the unit size of a biogas unit, the following mathematical equation must be achieved: Digester size (m³) = Daily feed-in (m³ day-1) × Retention time (day)

(1)

The digester size can be defined as the total size of the biogas unit, which includes the effective size of any volume occupied by the fermented material and the volume of gas storage. Size of the daily feed-in is the size of a mixture of dung with water added to the digester once daily or several times and the average concentration of total solids of 10%, where mixing the organic wastes with water depends on its water content. In the case of wet animal wastes, such as manure the proportion of mixing is 1:1. Generally, Storage capacity has to be calculated by average live weight of animals 27

kept in husbandry systems, amount of added water, periods of no fertilization of crops, and the animal species. In order to plan a biogas plant and to design a digester, several design parameters must be determined which are: ratio of gathered waste from manure canals to total waste, number of cows in farm, amount of manure produced by a cow which is usually 1.8 m3 cow-1 month-1, quantity of daily liquid organic matter deposition into the digester, hydraulic retention time, density and quantity of daily dry organic matter deposition into the digester, and digester load which is usually 2-4 kg m-3 day-1. The aforementioned design parameters are used to determine the total volume of the materials that are intended to be stored in the tank and are equal to the internal volume of the tank. Additionally, the designer should take into consideration that a part of the tank (about 10%) is empty and the substrates should not fill it, because it is the place where the gas will accumulate. Even in case of deg other storage tanks (e.g. liquid organic matter tank) it is required to leave 10% of the tank volume empty.

2. Types of digester During the last century a number of different types of flows in simple digester have been developed and they can be of the following kinds: (1) batch flow, (2) continuous flow, (3) continuously expanding, (4) plug flow, and (5) flow. The conventional digesters are those utilized to process liquid raw materials with a high content in solids, also called rural digesters, the fermentation chamber having a volume below 100 m3. Conventional digesters are installed without any type of mechanism to reduce the retention time during which the biomass remains inside are predominant; these systems are fed discontinuously and known as discontinuous-flow i.e. batch digesters, or fed periodically and known as continuous-flow digesters. Batch digesters are loaded at once, maintained closed for a convenient period, and the organic matter is fermented and then unloaded at a later time. It is quite a simple system with small operational requirements. Installation can be made in an anaerobic tank or in a series of tanks, depending on the biogas demand, availability and amount of raw materials to be utilized. Batch flow is most suitable for dry organic matters (solid materials), e.g. solid vegetable waste. This type of biowastes is fed into the digester as a single batch. The digester is opened, digestate is removed to be used as biofertilizer and the new batch replaces the digestate. The tank is then resealed and 28

ready for operation. Depending on the waste material and the operating temperature, a batch digester will slowly start producing biogas and increase the production with time and then drop-off after 4 to 8 weeks. Batch digesters are therefore best operated in groups, so that at least one digester is always producing biogas. Continuous digesters are usually requiring daily loading and residue management. The process is referred to as continuous since to every daily load corresponds a similar volume load of fermented material. The biomass inside the digester moves through by the difference in hydraulic heat, between the substrate entering the digester and the digestate coming out when unloading. Each load requires a retention time, usually between 14 to 40 days. Continuous digesters can have their retention period reduced by the introduction of agitation and heating. The disadvantage of these models is that the raw material needs to be diluted. The great advantage of these digesters over the batch type is that a single unit allows a continuous supply of biogas and biofertilizer and the continuous treatment of small amounts of waste (Florentino, 2003). Biogas production can be accelerated by continuously feeding the digester with small amounts of waste daily. If such a continuous feeding system is used, then it is essential to ensure that the digester is large enough to hold all the material that will be fed into the digester in the whole digestion cycle. One key issue is to implement two digesters, i.e. accomplishing the biodegradation of the organic waste through two stages, with the main part of the biogas is being produced in the first stage and the second stage serves as finishing stage of the digestion at a slower rate. Regarding the continuously expanding flow, the digester starts one third full and then filled in stages and later emptied. Concerning the plug flow, the wastes are added regularly at one end and over-flows the other. In the flow, a medium is provided. Two simple biogas digester designs have been developed, the Chinese fixed dome digester and the Indian floating cover biogas digester. The digestion process is the same in both digesters but the gas collection method is different in each. In the Indiantype digester, the water sealed cover of the digester rises as gas is produced and acts as a storage chamber, whereas the Chinese-type digester has a lower gas storage capacity and requires efficient sealing in order to prevent gas leakage. Both have been

29

designed for use with animal waste or dung. Additionally, there are also Philippine and Sri Lankan digesters.

a. Indian digester The Indian-type digester basically is comprised of a cylindrical body, gasometer, feed pit and outlet pit (Florentino, 2003). The digester is made using burnt-clay bricks and cement. The cylindrical dome is made of metal sheets and moves up and down as it stores and releases the biogas. The digester is operated in continuing method and often vertically, almost cylindrical built. The putridity space filled the ground and it has a dividing wall. This dividing wall improves and holds back the fresh slime gush again through short way. The gas is gathered in floating gas lock. The steel gas lock is provided with stir elements. The periodic destruction of swimming layer is performed using the manual stirring of gas lock. The requested gas pressure arises from the heaviness of the swimming gas lock. The gas pressure can basically be changed in the practice by putting things on the gas lock. This type is suitable for the homogeneous materials, as for the animals’ excrements that do not tend to build sinking layers. The green waste must be split. If it is mixed with huge allotments, then it will threat the digester with blockage. Generally, there are several designs of Indian digesters, thereof: floating gas holder type biogas plant (KVIC model), Deenbandhu model, and Pragati model. The KVIC model is composite unit of a masonry digester and a metallic dome, where the maintenance of constant pressure by upward and downward movement of the gas holder. The Deenbandhu model consists of segments of two spheres of different diameters ed at their base, where this model requires lower costs in comparison to KVIC model. The Pragati model is a combination of Deenbandhu and KVIC designs, where the lower part of the digester is semi spherical with conical bottom and the floating drum acts as gas storage.

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Figure 7: Indian-type digester (Florentino, 2003)

b. Chinese digester The Chinese-type model digester is comprised of a cylindrical body, two spherical domes, inlet pit, outlet pit and an inspection opening (Florentino, 2003). The digester is made using cement and bricks and it is a permanent structure. Just as in the Indian digester this has two drains to feed waste and to collect the composted waste. The biogas is collected in the upper chamber and the waste decomposes in the lower chamber. If the gas pressure exceeds the atmospheric pressure (1 bar) and there is no gas extracted from the dome, then the rot substrate squeezed from the reactor into the filled pipe, but often in the pool of counterpoise. If the produced gas is more than the up used gas, then the slime level will increase. If the up used gas is more than the produced gas during the gas extraction, then the slime level will sink and the rot slime will flow back. The volume of the counterpoise pool must be huge so that the repressed rot substrate can be digested at the highest gas volume. The gas pressure is not constant in the practice. It increases with the quantity of the stored gas. The gas must be regularly produced; therefore the gas pressure organizer or the swimming gas repository room is important.

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Owing to the fact that the biogas dome digesters are completely buried underground, the fermentation temperature should be under a day/night temperature change, only in a tolerance range from about ± 2 ºC. The difference between summer and winter is large and is subject to the climate zone. The biogas dome digester can be provided with stir. In small family household units, a mix concoction for the biogas dome digester is installed. Different building and construction forms of biogas dome digesters were proved for the Chinese digesters; so that there is a big number of building methods are used.

Figure 8: Chinese-type digester (Florentino, 2003)

3. Designs of digester The most common digester design is cylindrical. Digesters can be classified in horizontal and vertical designs Currently, vertical concrete or steel digesters with rotating propellers or immersion pumps for homogenization are widespread. Vertical tanks simply take feedstock in a pipe on one side, whilst digestate overflows through a pipe on the other side. In horizontal plug-flow systems, a more solid feedstock is used as a plug that flows through a horizontal digester at the rate it is fed-in. Vertical tanks are simpler and cheaper to operate, but the feedstock may not reside in the digester for the optimum period of time. Horizontal tanks are more expensive to build and operate, but the feedstock will neither leave the digester too early nor stay inside the digester for an uneconomically long period.

32

(a)

(b) Fig 10: Horizontal (a) and vertical (b) digester (Gronauer and Neser, 2003) Anaerobic digesters can be built either above or under the ground. An alternative is that a part of the digester can be buried. Anaerobic digesters constructed above ground are steel structures to withstand the pressure; therefore, it is simpler and cheaper to build the digester underground. Maintenance is, however, much simpler for digesters built above ground and a black coating will help provide some solar heating.

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CHAPTER V Biogas A major contributor to biogas production on farms Biogas typically refers to a mixture of different gases produced by the breakdown of organic matter in the absence of oxygen. Biogas can be produced from raw materials such as agricultural waste, manure, municipal waste, plant material, sewage, green waste or food waste. It is a renewable energy source and in many cases exerts a very small carbon footprint. Biogas can be produced by anaerobic digestion with anaerobic bacteria, which digest material inside a closed system, or fermentation of biodegradable materials. Biogas

is

primarily

methane

(CH

4) and carbon dioxide (CO2) and may have small amounts of hydrogen sulphide (H 2S), moisture and siloxanes. The gases methane, hydrogen, and carbon monoxide (CO) can be combusted or oxidized with oxygen. This energy release allows biogas to be used as a fuel; it can be used for any heating purpose, such as cooking. It can also be used in a gas engine to convert the energy in the gas into electricity and heat. Biogas can be compressed, the same way natural gas is compressed to CNG, and used to power motor vehicles. In the UK, for example, biogas is estimated to have the potential to replace around 17% of vehicle fuel. It qualifies for renewable energy subsidies in some parts of the world. Biogas can be cleaned and upgraded to natural gas standards, when it becomes bio methane.

1. Production Biogas is produced as landfill gas (LFG), which is produced by the breakdown of biodegradable waste inside a landfill due to chemical reactions and microbes, or as digested gas, produced inside an anaerobic digester. A biogas plant is the name often given to an anaerobic digester that treats farm wastes or energy crops. It can be produced using anaerobic digesters (air-tight tanks with different configurations). These plants can be fed with energy crops such as maize silage or biodegradable wastes 34

including sewage sludge and food waste. During the process, the microorganisms transform biomass waste into biogas (mainly methane and carbon dioxide) and digestate. The biogas is a renewable energy that can be used for heating, electricity, and many other operations that use a reciprocating internal combustion engine, such as GE Jenbacher or Caterpillar gas engines. Other internal combustion engines such as gas turbines are suitable for the conversion of biogas into both electricity and heat. The digestate is the remaining organic matter that was not transformed into biogas. It can be used as an agricultural fertiliser. There are two key processes: mesophilic and thermophilic digestion which is dependent on temperature. In experimental work at University of Alaska Fairbanks, a 1000-litre digester using psychrophiles harvested from "mud from a frozen lake in Alaska" has produced 200–300 liters of methane per day, about 20%–30% of the output from digesters in warmer climates.

2. Landfill gas Landfill gas is produced by wet organic waste decomposing under anaerobic conditions in a landfill. The waste is covered and mechanically compressed by the weight of the material that is deposited above. This material prevents oxygen exposure thus allowing anaerobic microbes to thrive. This gas builds up and is slowly released into the atmosphere if the site has not been engineered to capture the gas. Landfill gas released in an uncontrolled way can be hazardous since it can becomes explosive when it escapes from the landfill and mixes with oxygen. The lower explosive limit is 5% methane and the upper is 15% methane. The methane in biogas is 20 times more potent a greenhouse gas than carbon dioxide. Therefore, uncontained landfill gas, which escapes into the atmosphere may significantly contribute to the effects of global warming. In addition, volatile organic compounds (VOCs) in landfill gas contribute to the formation of photochemical smog.

35

3. Technical Biochemical oxygen demand (BOD) is a measure of the amount of oxygen required by aerobic micro-organisms to decompose the organic matter in a sample of water. Knowing the energy density of the material being used in the biodigester as well as the BOD for the liquid discharge allows for the calculation of the daily energy output from a biodigester. Another term related to biodigesters is effluent dirtiness, which tells how much organic material there is per unit of biogas source. Typical units for this measure are in mg BOD/litre. As an example, effluent dirtiness can range between 800–1200 mg BOD/litre in Panama. From 1 kg of decommissioned kitchen bio-waste, 0.45 m³ of biogas can be obtained. The price for collecting biological waste from households is approximately €70 per ton

4. Composition

The composition of biogas varies depending upon the origin of the anaerobic digestion process. Landfill gas typically has methane concentrations around 50%. Advanced waste treatment technologies can produce biogas with 55%–75% methane, which for reactors with free liquids can be increased to 80%-90% methane using in-situ gas 36

purification techniques. As produced, biogas contains water vapor. The fractional volume of water vapor is a function of biogas temperature; correction of measured gas volume for water vapor content and thermal expansion is easily done via simple mathematics which yields the standardized volume of dry biogas. In some cases, biogas contains siloxanes. They are formed from the anaerobic decomposition of materials commonly found in soaps and detergents. During combustion of biogas containing siloxanes, silicon is released and can combine with free oxygen or other elements in the combustion gas. Deposits are formed containing mostly 2)

silica or

(SiO silicates

(Si

xO y) and can contain calcium, sulfur, zinc, phosphorus. Such white mineral deposits accumulate to a surface thickness of several millimeters and must be removed by chemical or mechanical means. Practical and cost-effective technologies to remove siloxanes and other biogas contaminants are available.(broken link) For 1000 kg (wet weight) of input to a typical biodigester, total solids may be 30% of the wet weight while volatile suspended solids may be 90% of the total solids. Protein would be 20% of the volatile solids, carbohydrates would be 70% of the volatile solids, and finally fats would be 10% of the volatile solids. 5. Benefits In North America, use of biogas would generate enough electricity to meet up to 3% of the continent's electricity expenditure. In addition, biogas could potentially help reduce global climate change. High levels of methane are produced when manure is stored under anaerobic conditions. During storage and when manure has been applied to the land, nitrous oxide is also produced as a byproduct of the denitrification process. Nitrous oxide (N2O) is 320 times more aggressive than carbon dioxide and methane 21 times more than carbon dioxide.

37

By converting cow manure into methane biogas via anaerobic digestion, the millions of cattle in the United States would be able to produce 100 billion kilowatt hours of electricity, enough to power millions of homes across the United States. In fact, one cow can produce enough manure in one day to generate 3 kilowatt hours of electricity; only 2.4 kilowatt hours of electricity are needed to power a single 100-watt light bulb for one day. Furthermore, by converting cattle manure into methane biogas instead of letting it decompose, global warming gases could be reduced by 99 million metric tons or 4%.

6. Applications Biogas can be used for electricity production on sewage works, in a CHP gas engine, where the waste heat from the engine is conveniently used for heating the digester; cooking; space heating; water heating; and process heating. If compressed, it can replace compressed natural gas for use in vehicles, where it can fuel an internal combustion engine or fuel cells and is a much more effective displacer of carbon dioxide than the normal use in on-site CHP plants. a. Biogas upgrading Raw biogas produced from digestion is roughly 60% methane and 29% CO 2

with

trace

elements

of

H

2S; it is not of high enough quality to be used as fuel gas for machinery. The corrosive nature

of

H

2S alone is enough to destroy the internals of a plant. Methane in biogas can be concentrated via a biogas upgrader to the same standards as fossil natural gas, which itself has had to go through a cleaning process, and becomes biomethane. If the local gas network allows, the producer of the biogas may use their distribution networks. Gas must be very clean to reach pipeline quality and must be of the correct composition for the distribution network to accept. Carbon dioxide, water, hydrogen sulfide, and particulates must be removed if present. There are four main methods of upgrading: water washing, pressure swing adsorption, selexol adsorption, and amine gas treating. In addition to these, the use of membrane 38

separation technology for biogas upgrading is increasing, and there are already several plants operating in Europe and USA. The most prevalent method is water washing where high pressure gas flows into a column where the carbon dioxide and other trace elements are scrubbed by cascading water running counter-flow to the gas. This arrangement could deliver 98% methane with manufacturers guaranteeing maximum 2% methane loss in the system. It takes roughly between 3% and 6% of the total energy output in gas to run a biogas upgrading system. b. Biogas gas-grid injection Gas-grid injection is the injection of biogas into the methane grid (natural gas grid). Injections includes biogasuntil the breakthrough of micro combined heat and power two-thirds of all the energy produced by biogas power plants was lost (the heat), using the grid to transport the gas to customers, the electricity and the heat can be used for on-site generation resulting in a reduction of losses in the transportation of energy. Typical energy losses in natural gas transmission systems range from 1% to 2%. The current energy losses on a large electrical system range from 5% to 8%. c. Biogas in transport

Figure 11: biogas in rail 39

"Biogaståget Amanda" ("The Biogas Train Amanda") train near Linköping station, Sweden If concentrated and compressed, it can be used in vehicle transportation. Compressed biogas is becoming widely used in Sweden, Switzerland, and . A biogaspowered train, named Biogaståget Amanda (The Biogas Train Amanda), has been in service in Sweden since 2005. Biogas powers automobiles. In 1974, a British documentary film titled Sweet as a Nut detailed the biogas production process from pig manure and showed how it fueled a custom-adapted combustion engine. In 2007, an estimated 12,000 vehicles were being fueled with upgraded biogas worldwide, mostly in Europe. d. Measuring in biogas environments Biogas is part of the wet gas and condensing gas (or air) category that includes mist or fog in the gas stream. The mist or fog is predominately water vapor that condenses on the sides of pipes or stacks throughout the gas flow. Biogas environments include wastewater digesters, landfills, and animal feeding operations (covered livestock lagoons). Ultrasonic flow meters are one of the few devices capable of measuring in a biogas atmosphere. Most thermal flow meters are unable to provide reliable data because the moisture causes steady high flow readings and continuous flow spiking, although there are single-point insertion thermal mass flow meters capable of accurately monitoring biogas flows with minimal pressure drop. They can handle moisture variations that occur in the flow stream because of daily and seasonal temperature fluctuations, and for the moisture in the flow stream to produce a dry gas value.

40

CHAPTER VI Bio-fuels:A biofuel is a fuel that is derived from biological materials, such as plants and animals. Also biofuel can still be seen as fuel derived from organic matter (obtained directly from plants, or indirectly from agricultural, commercial, domestic, and/or industrial wastes).[1] Examples of this carbon fixation occur in plants and microalgae through the process of photosynthesis. These fuels are made by a biomass conversion (biomass refers to recently living organisms, most often referring to plants or plant-derived materials). This biomass can be converted to convenient energy containing substances in three different ways: thermal conversion, chemical conversion, and biochemical conversion. This biomass conversion can result in fuel in solid, liquid, or gas form. This new biomass can be used for biofuels. Biofuels have increased in popularity because of rising oil prices and the need for energy security. Bioethanol is an alcohol made by fermentation, mostly from carbohydrates produced in sugar or starch crops such as corn, sugarcane, or sweet sorghum. Cellulosic biomass, derived from non-food sources, such as trees and grasses, is also being developed as a feedstock for ethanol production. Ethanol can be used as a fuel for vehicles in its pure form, but it is usually used as a gasoline additive to increase octane and improve vehicle emissions. Bioethanol is widely used in the USA and in Brazil. Current plant design does not provide for converting the lignin portion of plant raw materials to fuel components by fermentation. Biodiesel can be used as a fuel for vehicles in its pure form, but it is usually used as a diesel additive to reduce levels of particulates, carbon monoxide, and hydrocarbons from diesel-powered vehicles. Biodiesel is produced from oils or fats using transesterification and is the most common biofuel in Europe. In 2010, worldwide biofuel production reached 105 billion liters (28 billion gallons US), up 17% from 2009, and biofuels provided 2.7% of the world's fuels for road transport, a contribution largely made up of ethanol and biodiesel. Global ethanol fuel production reached 86 billion liters (23 billion gallons US) in 2010, with the United States and Brazil as the world's top producers, ing together for 90% of global 41

production. The world's largest biodiesel producer is the European Union, ing for 53% of all biodiesel production in 2010. As of 2011, mandates for blending biofuels exist in 31 countries at the national level and in 29 states or provinces. The International Energy Agency has a goal for biofuels to meet more than a quarter of world demand for transportation fuels by 2050 to reduce dependence on petroleum and coal. The production of biofuels also led into a flourishing automotive industry, where by 2010, 79% of all cars produced in Brazil were made with a hybrid fuel system of bioethanol and gasoline. There are various social, economic, environmental and technical issues relating to biofuels production and use, which have been debated in the popular media and scientific journals. These include: the effect of moderating oil prices, the "food vs fuel" debate, poverty reduction potential, carbon emissions levels, sustainable biofuel production, deforestation and soil erosion, loss of biodiversity, impact on water resources, rural social exclusion and injustice, shantytown migration, rural unskilled unemployment, and nitrous oxide (NO2) emissions.

1. Boiler Types:Typical boiler types that burn biomass fuels include stoker-fired, bubbling fluidized bed and circulating fluidized bed. Biomass is co-fired with other solid fuels in pulverized fuel and cyclone boilers. Generally speaking, when compared to fluidized bed boilers, stoker-fired boilers can be lower in cost to procure, install and maintain. Fluidized bed boilers provide much more fuel flexibility than stoker-fired boilers.

2. Biomass Characteristics:Wood fuels can come from many different sources. Some of the highest volume sources are sawmill bark and sawdust, tree farm harvest, forest residue, storm damage, diseased tree removal, urban cleanup, construction recycling, manufacturing waste streams and shredded railroad ties. Wood is usually chipped or ground to a maximum size of three inches for use as a fuel in stoker-fired or fluidized sawdust or1 inch ground material. One recent application in a cyclone boiler used ¼ inch dry wood shavings. Municipal waste is generally burned in mass-burn facilities or processed to produce Refuse derived fuel (RDF). RDF is produced using shredders, magnets, screens and air classification. RDF is usually sized to a maximum of 6 inches. 42

3. Environmental Impact:The use of biomass energy has many unique qualities that provide environmental benefits. It can help mitigate climate change, reduce acid rain, soil erosion, water pollution and pressure on landfills, provide wildlife habitat, and help maintain forest health through better management.

Fig 12: Environmental Impact 4. Climate Change:Climate change is a growing concern world-wide. Human activity, primarily through the

combustion of fossil fuels, has released hundreds of millions of tons of so-

called greenhouse gases (GHGs) into the atmosphere. GHGs include such gases as carbon dioxide (CO2) and methane (CH4). The concern is that all of the greenhouse gases in the atmosphere will change the Earth’s climate, disrupting the entire biosphere which currently s life as we know it. Biomass energy technologies can help minimize this concern. Although both methane and carbon dioxide pose significant threats, CH4 is 20 times more potent (though shorter-lived in the atmosphere) than CO2. Capturing methane from landfills, wastewater treatment, and manure lagoons prevents the methane from being vented to the atmosphere and allows the energy to be used to generate electricity or power motor vehicles. All 43

crops, including biomass energy crops, sequester carbon in the plant and roots while they grow, providing a carbon sink. In other words, the carbon dioxide released while burning biomass is absorbed by the next crop growing. This is called a closed carbon cycle. In fact, the amount of carbon sequestered may be greater than that released by combustion because most energy crops are perennials; they are harvested by cutting rather than uprooting. Thus the roots remain to stabilize the soil, sequester carbon and to regenerate the following year. 5. AcidRain:Acid rain is caused primarily by the release of sulphur and nitrogen oxides from the combustion of fuels. Acid rain has been implicated in the killing of lakes, as well as impacting humans and wildlife in other ways. Since biomass has no sulphur content, and easily mixes with coal, co-firing is a very simple way of reducing sulphur emissions and thus, reduce acid rain. Co-firing refers to burning biomass tly with coal in a traditionally coal-fired power plant or heating plant. 6. SoilErosion & waterpollution:Biomass crops can reduce water pollution in a number of ways. Energy crops can be grown on more marginal lands, in floodplains, and in between annual crops areas. In all these cases, the crops stabilize the soil, thus reducing soil erosion. They also reduce nutrient run-off, which protects aquatic ecosystems. Their shade can even enhance the habitat for numerous aquatic organisms like fish. Furthermore, because energy crops tend to be perennials, they do not have to be planted every year. Since farm machinery spends less time going over the field, less soil compaction and soil disruption takes place. Another way biomass energy can reduce water pollution is by capturing the methane, through anaerobic digestion, from manure lagoons on cattle, hog and poultry farms. These enormous lagoons have been responsible for polluting rivers and streams across the country. By utilizing anaerobic digesters, the farmers can reduce odour, capture the methane for energy, and create either liquid or semisolid soil fertilizers which can be used on-site or sold. 7. Barriers:

Biomass produces greenhouse emissions.



It takes considerable energy to produce biofuels from certain feedstock, resulting in less than desirable energy returns on energy invested (EROEI).



Biomass collection is difficult. 44



Biomass crops not available all year.



Still an expensive source, both in of producing the biomass and converting it to alcohols

8.Biomass Energy in India:Biomass contributes over a third of primary energy in India. Biomass fuels are predominantly Used in rural households for cooking and water heating, as well as by traditional and artisan Industries. India had a cumulative installed biomass capacity of about 520MW at the start of the Eleventh plan (2007-2012), the current plan period. The Ministry of New and Renewable Energy (MNRE) had set an ambitious target of 500MW for this plan period. The ministry has now informed that they have achieved a capacity of about 460MW already in this plan period. This is commendable and they expect that the target would be more than sured. The key to the success is that the biomass power projects are set-up as commercial projects through private investment at viable locations depending upon availability of biomass. Central Financial Assistance is provided to the Financial Institutions for reduction in the loan amount sanctioned for the projects. Further MNRE has mentioned that they are encouraging setting up of biomass power projects through various technological routes namely combustion, gasification and cogeneration. Various fiscal and financial incentives such as capital subsidy linked with project capacity and fiscal incentives such as concessional customs duty on import of machinery and components, excise duty exemption, accelerated depreciation on major components and relief from taxes are being provided for setting up of biomass power projects. Besides, preferential tariff is being provided for sale of power from biomass power projects. According to the most recent data given by MNRE, about 980 MW of biomass power has been commissioned and about 380MW of capacity is under implementation. The state wise capacity of biomass power projects commissioned is shown in the chart below:-

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Figure 13: Pie chart on Capacity of Biomass Projects In India 9. Large Scale Electricity Generation Programs:The future of modern biomass power program rests on its competitive ability vis-à-vis other centralized electricity generation technologies. Policies for realizing biomass electric Power potential through modern technologies under competitive dynamics have a recent origin in India. The biomass electricity program took shape after MNES appointed the task force in 1993 and recommended the thrust on bagasse based cogeneration. The focus of modern Biomass program is on the cogeneration, especially in sugar industry. A cogeneration Potential of17, 000 MW power is identified, with 6000 MW in sugar industry alone (Rajan, 1995). Program for biomass combustion based power has even more recent origin. It began in 1994 as a Pilot Program launched with approval of two 5 MW projects. Interest subsidy program on the lines of that for the bagasse based co-generation was extended in 1995. The program also initiated grid connected biomass gasification R&D-cum-Demonstration Project of 500 Kilo Watt (KW) capacities. A decentralized electricity generation program initiated in 1995 provided for total of 10 to 15 MW of small decentralized projects aimed at energy self sufficiency in electricity deficient rural locales. The program aims to utilize some of the 350 million tons of agricultural and agro-industrial residues produced annually in India. The cost of electricity generation from these plants is anticipated to be quite competitive at Rs. 1.8 per KWh.

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10. Cost of Electricity Generation by Biomass-based Power Stations:There is a general perception that the cost of electricity generated by renewable energy technologies is always higher than electricity generated by fossil fuel sources. While this

is

true in many places, it is no longer valid for the rural areas of rural India. In most of the Indian villages diesel generators are often the only source of power but power from biomass gasifier based plants are considerably cheaper where ever biomass is available. Even for dual fuel operation where 20 % diesel is used, the generation costs are lower, especially

with

high

running hours and loads. The savings are dramatic when pure gas engines are used. Even when grid power is available, the actual cost of power at the point of consumption is very high largely due to line losses in transmission and distribution. High subsidies and financial losses keep the power price low for agricultural pumps but now that industrial and commercial consumers pay the actual cost of power, the biomass gasification based electricity can easily compete when pure gas engines are used. 11. Future of Biomass Energy in India:Future of biomass energy depends on providing reliable energy services at competitive cost. In India, this will happen only if biomass energy services can compete on a fair market. Policy priorities should be to orient biomass energy services towards market and to reform the market towards fair competition by internalizing the externalities of competing energy resources. Most economical option is utilization of waste materials. Potential availability of agro residues and wood processing waste in India can sustain 10,000 MW power. Biomass waste however shall be inadequate to the growing demands for biomass resources. Sustained supply of biomass shall require production of energy crops (e.g. wood fuel, Plantations, sugar cane as feedstock for ethanol) and wood plantations for meeting growing Non-energy needs. Land supply, enhanced biomass productivity, economic operations of Plantations and logistics infrastructure are critical areas which shall determine future of biomass in India. Policy for a transition towards a biomass based civilization in India.

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CHAPTER VII CONCLUSION:Biomass fuels can serve an important role in a utility’s model to produce renewable energy. With careful planning and execution, an Owner can successfully integrate biomass fueled plants into its generation mix. There are several reliable technologies Owners may adopt to burn biomass. Equipment manufacturers continually offer new innovations to handle, store, transport and burn biomass fuels. Biomass fuels present unique challenges for all s. Care must be taken to choose and locate the appropriate fuel to meet a facility’s needs, and also choose the appropriate equipment to ensure long-term economical plant operations. Owners should dedicate resources to continuously work with suppliers, processors and transporters to develop new supply options.

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REFERENCES:  En.wikipedia.org/wiki/biomass  Non-Conventional Energy Sources By G.D. Rai  www.decisioncraft.com/energy/papers/ecc/re/biomass/bti.pdf  edugreen.teri.res.in/explore/renew/biomass.htm Shukla, P.R (1997), Biomass Energy in India, Conference Proceedings - Biomass Energy: Key Issues and Priority Needs, International Energy Agency, Paris,

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